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Continental alkaline magmatism produces a wide variety of igneous rock types because of varying degrees of partial melting of heterogenous mantle sources, fractional crystallization, and magma contamination during transit through the continental crust. The Mount Overlord Volcanic Field (MOVF) is a continental alkaline volcanic province in northern Victoria Land, Antarctica. Mount Overlord and the associated vents that make up the volcanic field are some of the least-explored volcanic rocks in the western Ross Sea. The MOVF sits within the Transantarctic Mountains, which form the rift shoulder of the extensive West Antarctic Rift System. The compositions of volcanic rocks in the MOVF range widely from basanite to evolved trachyte and comendite with a suite of intermediate rock types. Here we present 40Ar/39Ar ages, petrography, and whole-rock and mineral geochemistry to establish the temporal and magmatic evolution of the magmatic system. Volcanic activity occurred from 21.2 to 6.9 Ma, making it one of the longest records of volcanism in the western Ross Sea area. Mount Rittmann, an active volcano that is part of the MOVF, is not discussed here but extends the timing of volcanism of the MOVF into the Holocene. At Mount Overlord and surrounding areas, there were eruptions of lava flows, domes, and pyroclastic rocks. Localized deposits of hyaloclastites formed by magma-ice interactions provide an insight into former ice levels. Geochemically the MOVF shows a single magma differentiation trend except for Navigator Nunatak lavas which have a potassic affinity rarely seen in northern Victoria Land. Partial melting of an amphibole-bearing mantle lithology at or near the base of the continental lithospheric mantle (CLM) was the main source of the parental basaltic magmas. Polybaric crystal fractionation of the primary basaltic magmas mainly occurred at lower crustal depths and involved fractionation of clinopyroxene, olivine, kaersutite, feldspars, biotite, Fe–Ti oxides, apatite, and sodalite. Crustal assimilation of c. 10% granite harbor igneous complex granitoids was important in the evolution of intermediate composition magmas. Trachyte, phonolite, and comendite magmas stagnated and evolved at shallow crustal depths (c. <8 km). Over 95% crystal fractionation was required to generate the comendites. Extraction of the comendite melt from a felsic crystal mush was an important process. The potassic Navigator Nunatak magma required partial melting of phlogopite-bearing metasomatized CLM. The metasomes had ‘HIMU-like’ or FOZO isotopic compositions that ultimately originated from recycling of materials in the mantle. The MOVF displays a stronger affinity toward FOZO than other northern Victoria Land basaltic rocks. This suggests that the interaction between parental melt and juvenile CLM was limited, which is similar to volcanic rocks from the oceanic Adare Basin seamounts. Our result emphasizes the critical importance of a thick CLM for the genesis of diverse alkaline magma compositions in a continental rift system. 

Two series of lactone-terminated alkanethiol adsorbates with five- and six-membered lactone groups, γ-COCnSH and δ-COCnSH (n = 11, 12), were synthesized and employed to create nanoscale self-assembled monolayers (SAMs) on gold substrates to mimic the properties of commercially available poly(lactic-co-glycolic acid) (PLGA) and poly(glycolic acid) (PGA) surfaces. 1H and 13C nuclear magnetic resonance (NMR) were employed to characterize the adsorbate molecules. The thicknesses of the corresponding self-assembled monolayers (SAMs) were evaluated by ellipsometry. The conformational characteristics of the SAMs were analyzed using polarization modulation infrared reflection adsorption spectroscopy (PM-IRRAS), with a focus on the C-H antisymmetric stretching vibrations of the alkyl spacers. To evaluate the packing densities of the monolayers, X-ray photoelectron spectroscopy (XPS) measurements were performed. Separately, contact angle measurements provided insights into the wettability of the surfaces. Remarkably, the contact angle data across a broad range of probe liquids for the γ-COC11SH and γ-COC12SH SAMs were consistently similar to each other and to the contact angle values of the PLGA surface, rather than to PGA. This finding suggests that the lactone-terminated SAMs investigated in this study effectively mimic nanoscale polyester surfaces, enabling the exploration of interfacial properties of polyesters in the absence of swelling and/or surface reconstruction phenomena. 

A central problem in modern condensed matter physics is the understanding of materials with strong electron correlations. Despite extensive work, the essential physics of many of these systems is not understood and there is very little ability to make predictions in this class of materials. In this manuscript we share our personal views on the major open problems in the field of correlated electron systems. We discuss some possible routes to make progress in this rich and fascinating field. This manuscript is the result of the vigorous discussions and deliberations that took place at Johns Hopkins University during a three-day workshop January 27, 28, and 29, 2020 that brought together six senior scientists and 46 more junior scientists. Our hope, is that the topics we have presented will provide inspiration for others working in this field and motivation for the idea that significant progress can be made on very hard problems if we focus our collective energies. 

Abstract New emerging low‐dimensional such as 0D, 1D, and 2D nanomaterials have attracted tremendous research interests in various fields of state‐of‐the‐art electronics, optoelectronics, and photonic applications due to their unique structural features and associated electronic, mechanical, and optical properties as well as high‐throughput fabrication for large‐area and low‐cost production and integration. Particularly, photodetectors which transform light to electrical signals are one of the key components in modern optical communication and developed imaging technologies for whole application spectrum in the daily lives, including X‐rays and ultraviolet biomedical imaging, visible light camera, and infrared night vision and spectroscopy. Today, diverse photodetector technologies are growing in terms of functionality and performance beyond the conventional silicon semiconductor, and low‐dimensional nanomaterials have been demonstrated as promising potential platforms. In this review, the current states of progress on the development of these nanomaterials and their applications in the field of photodetectors are summarized. From the elemental combination for material design and lattice structure to the essential investigations of hybrid device architectures, various devices and recent developments including wearable photodetectors and neuromorphic applications are fully introduced. Finally, the future perspectives and challenges of the low‐dimensional nanomaterials based photodetectors are also discussed. 

People often face barriers to selecting self-tracking tools that support their goals and needs, resulting in tools not meeting their expectations and ultimately abandonment. We therefore examine how people approach selecting self-tracking apps and investigate how technology can better support the process. Drawing on past literature on how people select and perceive the features of commercial and research tracking tools, we surface seven attributes people consider during selection, and design a low-fidelity prototype of an app store that highlights these attributes. We then conduct semi-structured interviews with 18 participants to further investigate what people consider during selection, how people select self-tracking apps, and how surfacing tracking-related attributes could better support selection. We find that people often prioritize features related to self-tracking during selection, such as approaches to collecting and reflecting on data, and trial apps to determine whether they would suit their needs. Our results also show potential for technology surfacing how apps support tracking to reduce barriers to selection. We discuss future opportunities for improving self-tracking app selection, such as ways to enhance existing self-tracking app distribution platforms to enable people to filter and search apps by desirable features. 

Large modulation of the microphase separated morphology and structural color of PS-b-PLA BBCPs using single materials by exploiting selective solubility of the two blocks in a series of structurally similar solvents.